反応 #2076087

反応方程式

4-bromo-1-(bromomethyl)-2-nitrobenzene

sodium methanethiolate

→

title compound

収率 105.8%

(4-Bromo-2-nitrophenyl)methyl sulfide

収率 105.8%

溶媒

tetrahydrofuran

反応条件

後処理

1. 1
   その他The solvent was evaporated
2. 2
   workup.ADDITIONchloroform (50 ml) was added
3. 3
   その他the rsidual solid was removed by filtration

実験手順

A suspension of 4-bromo-1-(bromomethyl)-2-nitrobenzene (1.0 g) and sodium methanethiolate (0.285 g) in tetrahydrofuran (20 ml) was stirred under nitrogen for 60 h. The solvent was evaporated, chloroform (50 ml) was added and the rsidual solid was removed by filtration. The filtrate was comncentrated under vacuum to give the title compound (0.89 g).

出典