反応 #2063056

反応方程式

p-nitrobromobenzene

styrene

triethylamine

propylene carbonate

→

p-nitrostilbene

溶媒

diethyl ether dichloromethane

反応条件

後処理

1. 1
   workup.ADDITIONis added
2. 2
   ろ過the mixture is filtered

実験手順

Under argon, a solution containing 218 mg of p-nitrobromobenzene, 141 mg of styrene, 0.3 ml of triethylamine, and 1 ml of propylene carbonate stabilized colloid solution with a palladium content of 4.023 mg is heated at 130° C. with stirring in a sealed vessel for 4.5 h. At the end of the reaction, 2 ml of diethyl ether/dichloromethane (1:1) is added, and the mixture is filtered. The yield of desired product as determined by GC is 96%.

出典