反応 #2024274

反応方程式

1,2-dichloroethane

trichlorosilane

→

1,2-bis(trichlorosilyl)ethane

収率 54.0%

反応条件

後処理

1. 1
   workup.DISTILLATIONThe resulting mixture was distilled

実験手順

In the same apparatus and procedure as Example 1 above, 0.44 g (1.50 mmol) of tetrabutylphosphonium chloride, 0.74 g (7.5 mmol) of 1,2-dichloroethane, and 10.16 g (75.0 mmol) of trichlorosilane were reacted at 150° C. for 10 hrs. The resulting mixture was distilled to give 1.09 g of 1,2-bis(trichlorosilyl)ethane (yield; 54%).

出典