反応 #1985928

ord-e3d708cb90714f64be0ed0e7f342b45e

反応方程式

CN(C)[C@@H]1C(=O)C(C(N)=O)=C(O)[C@@]2(O)C(=O)C3=C(O)c4c(O)ccc(Cl)c4[C@@H](O)[C@H]3C[C@@H]12
DMcT
→
CN(C)[C@@H]1C(=O)C(C(N)=O)=C(O)[C@@]2(O)C(=O)C3=C(O)c4c(O)ccc(Cl)c4[C@@H](O)[C@H]3C[C@@H]12.CN1CCCC1=O
DMcT NMP

反応物

CN(C)[C@@H]1C(=O)C(C(N)=O)=C(O)[C@@]2(O)C(=O)C3=C(O)c4c(O)ccc(Cl)c4[C@@H](O)[C@H]3C[C@@H]12
DMcT
—
( 1.5 )

試薬

なし

溶媒

CN1CCCC1=O
NMP

反応条件

詳細条件
See reaction.notes.procedure_details.

実験手順

One point five (1.5) g (0.01 mole) of DMcT monomer powder were dissolved in 5 g of NMP to obtain a yellowish transparent viscous DMcT-NMP solution. To this solution, 2.5 g (0.015 mole) of polyaniline powder in a de-doped and reduced state ("ANILEAD" available from Nitto Denko Corp., Japan) were added and the combined solution was then heated at 80° C. in a sealed container, whose inner atmosphere was replaced by an inert gas, to obtain a black purple liquid.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US05571292uspto-grants-1996_11