反応 #1960516

ord-1ce217c034a24955a38896e73a92e6af

反応方程式

[Zn]
Zn
O=[PH2]O
H3PO2
O.O.O.O.O.O.O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Zn+2]
zinc nitrate hexahydrate
→
O=P([O-])([O-])[O-].O=P([O-])([O-])[O-].[Zn+2].[Zn+2].[Zn+2]
Zinc Phosphate

反応物

[Zn]
Zn
O=[PH2]O
H3PO2
O.O.O.O.O.O.O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Zn+2]
zinc nitrate hexahydrate
—
Zn(NO3)2.6H2O
—
Zn3(PO4)2

試薬

なし

溶媒

O
water

反応条件

詳細条件
See reaction.notes.procedure_details.

後処理

  1. 1
    その他to form a clear, colorless solution

実験手順

An aqueous solution of 13.67 g 50 wt % H3PO2 was combined with 5.00 g deionized water to form a clear, colorless solution contained in a 250 ml Pyrex beaker. To this solution was added 46.23 g zinc nitrate hexahydrate salt, Zn(NO3)2.6H2O (Aldrich Chemical Co., Inc. #22, 873-7, CAS #10196-18-6), equivalent to 21.97 wt. % Zn. The molar ratio of [Zn]2+/[PO4]−3 in this mixture was 3/2 and the equivalent solids level [as Zn3(PO4)2] was 27.5 wt. %.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US08303976B2uspto-grants-2012_11