反応 #1929051

ord-e1c48d6ba812406c9fb07921d79de211

反応方程式

CCC(O)CCCCCCCCCCCCCCC(=O)O
16-hydroxystearic acid
CC(=O)OI1(OC(C)=O)(OC(C)=O)OC(=O)c2ccccc21
Dess-Martin reagent
→
CCC(=O)CCCCCCCCCCCCCCC(=O)O
16-oxostearic acid

反応物

CCC(O)CCCCCCCCCCCCCCC(=O)O
16-hydroxystearic acid
CC(=O)OI1(OC(C)=O)(OC(C)=O)OC(=O)c2ccccc21
Dess-Martin reagent

試薬

なし

反応条件

詳細条件
See reaction.notes.procedure_details.

実験手順

16-hydroxystearic acid was selectively oxidized with Dess-Martin reagent to yield 16-oxostearic acid. The crude product was purified by chromatography using silica gel as separating agent.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US08945897B2uspto-grants-2015_02