反応 #1925219

ord-3d314823161e4c64aa9131876a1f82ac

反応方程式

O=S(=O)(Cl)c1c(F)c(F)c(F)c(F)c1F
Pentafluorobenzenesulfonyl chloride
C[N+](C)(C)C.[OH-]
tetramethylammonium hydroxide
C[N+](C)(C)C.O=S(=O)([O-])c1c(F)c(F)c(F)c(F)c1F
tetramethylammonium pentafluorobenzenesulfonate

溶媒

反応条件

詳細条件
See reaction.notes.procedure_details.

実験手順

Pentafluorobenzenesulfonyl chloride (25 g) was dissolved in 100 ml of methanol under ice cooling, and 100 g of a 25% aqueous solution of tetramethylammonium hydroxide was slowly added thereto, followed by stirring at room temperature for 3 hours. Thus, a solution of tetramethylammonium pentafluorobenzenesulfonate was obtained. This solution was used for salt interchange with a sulfonium salt and an iodonium salt.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US06673512B1uspto-grants-2004_01