反応 #1914821

反応方程式

dichloro(β-cyano)ethoxyphosphine

diisopropylethylamine

diisopropylamine

→

Diisopropylaminochloro(β-cyano)ethoxyphosphine

溶媒

dichloromethane

反応条件

後処理

1. 1
   その他the reaction mixture is ready for the next step reaction

実験手順

To a solution of 0.54 mL(4.0 mmol) of dichloro(β-cyano)ethoxyphosphine in 40 mL of dichloromethane cooled in an ice-water bath was added 10 mL of diisopropylethylamine, followed by adding 0.64 mL (4.0 mmol) of diisopropylamine under Argon. The reaction mixture was warmed up to room temperature and stirred for 2 h. After adding 0.1 gm of DMAP into the solution, the reaction mixture is ready for the next step reaction.

出典