反応 #1904057
ord-a0cf59c0cb6e46628e44f8a7052ba0fd
反応方程式
1-(2-amino-5-bromo-phenyl)-ethanone
2-thiazolyl lithium
→
1-(2-Amino-5-bromo-phenyl)-1-thiazol-2-yl-ethanol
反応条件
詳細条件
See reaction.notes.procedure_details.
実験手順
Prepared from 1-(2-amino-5-bromo-phenyl)-ethanone and 2-thiazolyl lithium generally according to the procedure described in example 1. 1H-NMR (DMSO-d6) δ 7.70 (d, J=3.3 Hz, 1H), 7.64 (d, J=3.2 Hz, 1H), 7.28 (d, J=2.4 Hz, 1H), 7.10 (dd, J=8.5, 2.4 Hz, 1H), 6.92 (s, 1H), 6.55 (d, J=8.5 Hz, 1H), 5.50 (s, 2H), 1.90 (s, 3H).