反応 #1885010

ord-84a817739218448f800ce098b60147f5

反応方程式

C=Cc1ccccc1
styrene
C=CC(=O)OCCCC
butyl acrylate
C=CC(=O)O
acrylic acid
CCCCCCCCCCCCS
dodecanethiol
CCCCCCCCCCCCOS(=O)(=O)c1ccccc1.[Na]
sodium dodecylbenzenesulfonate
C=CC(=O)O.C=CC(=O)OCCCC.C=Cc1ccccc1
Styrene Butyl Acrylate Acrylic Acid

溶媒

反応条件

詳細条件
See reaction.notes.procedure_details.

後処理

  1. 1
    その他In a reactor equipped with a reflux condenser, a stirrer
  2. 2
    workup.ADDITIONa nitrogen-introducing pipe

実験手順

In a reactor equipped with a reflux condenser, a stirrer, a nitrogen-introducing pipe, and a monomer dripping funnel, 3.3 parts of sodium dodecylbenzenesulfonate is dissolved in 3,824 parts of ion exchange water. Subsequently, 30.6 parts of styrene, 9.4 parts of butyl acrylate, 1.2 parts of acrylic acid dimer, and 0.3 parts of dodecanethiol are added thereto, and thoroughly stirred at room temperature for emulsification stabilization (emulsified liquid 1).

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US08343703B2uspto-grants-2013_01