反応 #1876821

ord-a9e2bc7ece64422aa680ac0d6978bd7c

反応方程式

O=C(Cl)C12CC3CC(O)(C1)CC(C(=O)Cl)(C3)C2
1,3-dichloroformyl-5-hydroxyadamantane
CN(C)C
trimethylamine
C[Si](C)(C)Cl
trimethylsilyl chloride
C[Si](C)(C)OC12CC3CC(C(=O)Cl)(C1)CC(C(=O)Cl)(C3)C2
1,3-dichloroformyl-5-trimethylsiloxyadamantane

反応条件

詳細条件
See reaction.notes.procedure_details.

後処理

  1. 1
    その他Reaction
  2. 2
    その他was carried out at room temperature

実験手順

The 1,3-dichloroformyl-5-hydroxyadamantane was dissolved in methylene chloride. To this solution were added a small amount of trimethylamine, and then an eguimolar amount of trimethylsilyl chloride. Reaction was carried out at room temperature to obtain 1,3-dichloroformyl-5-trimethylsiloxyadamantane.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US07070905B2uspto-grants-2006_07