反応 #1876819

反応方程式

1,3-dihydroxyadamantane

acetic acid-acetic anhydride

hydroxyadamantane

→

1,3,5-trihydroxyadamantane

反応条件

後処理

1. 1
   温度with heating
2. 2
   その他the reaction for 8 hours
3. 3
   その他to obtain
4. 4
   その他This mixture was partitioned by high performance liquid chromatography

実験手順

One mol of 1,3-dihydroxyadamantane was stirred in an acetic acid-acetic anhydride solution of CrO3, oxidizing agent, with heating. After carrying out the reaction for 8 hours, the reaction solution was neutralized to obtain a mixture of polyhydroxylated compounds of hydroxyadamantane. This mixture was partitioned by high performance liquid chromatography to obtain 1,3,5-trihydroxyadamantane.

出典