反応 #1797501

ord-984e2a73d7d14cc7b3a454edf29d3d16

反応方程式

COc1ccc(-c2cc(=O)c3c(OC)c(OC)c(OC)c(OC)c3o2)cc1
tangeretin
C=CCc1cc(OC)c2c(c1)OCO2
Myristicin
C=CCc1cc(OC)c2c(c1OC)OCO2
apiole
CC(C)=CCC[C@](C)(O)C1CC=C(C)CC1
bisabolol
CC(C)=CCC/C(C)=C/COc1c2ccoc2cc2oc(=O)ccc12
bergamotin
C=CCc1ccc(OC)c(OC)c1
Methyleugenol

反応条件

詳細条件
See reaction.notes.procedure_details.

後処理

  1. 1
    その他Juvocimene was synthesized

実験手順

Chemicals were purchased from Sigma-Aldrich Chemical Company (St. Louis, Mo.) unless noted. Plant oils were manufactured by Aura Cacia (Weaverville, Calif.). Juvocimene was synthesized as described (Mestres, R. and E. Munoz, 1996, Synthetic Comm., 26:1309-1319). Myristicin, apiole, bergamotin, tangeretin, bisabolol, and cucurbitacin were obtained from Indofine Chemical Company (Somerville, N.J.). Methyleugenol was provided by the Batelle Chemical Company (Columbus, Ohio). Man-made insecticides were purchased from Chem Service (West Chester, Pa.). The precocene-like suicide substrate 3,4-dimethoxyisopentenylphenol was prepared as described Bowers, W. S., et al., 1976, Science, 217:647-648) except that a 3,4-dimethoxylated reactant was used.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US07790377B2uspto-grants-2010_09