反応 #1797479

反応方程式

C3F7OCF═CF2

methanol

t-amylperoxybenzoate

→

C3F7OCFHCF2CH2OH

反応条件

後処理

1. 1
   その他at 106° C
2. 2
   その他The product reaction mixture
3. 3
   洗浄was washed with water
4. 4
   workup.DISTILLATIONdistilled
5. 5
   その他=115-117° C.

実験手順

C3F7OCFHCF2CH2OH was prepared by the reaction of C3F7OCF═CF2 (53 g, 0.2 mol) with methanol (63.7 g, 2.0 mol) using t-amylperoxybenzoate (1.0 g) as free radical initiator at 106° C. The product reaction mixture was washed with water and distilled and the distillation fraction of b.r.=115-117° C. used in the next step.

出典