反応 #1797472

ord-7338affa70ff445b8d0a9b1dcee742d4

反応方程式

O.O.O.O.O.O.O=[N+]([O-])[O-].O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Bi+3]
bismuth nitrate hexahydrate
O=C(O)CN(CCN(CC(=O)O)CC(=O)O)CC(=O)O
EDTA
→
O=C(O)CN(CCN(CC(=O)O)CC(=O)O)CC(=O)O.[Bi]
Bismuth EDTA

反応物

O.O.O.O.O.O.O=[N+]([O-])[O-].O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Bi+3]
bismuth nitrate hexahydrate
O=C(O)CN(CCN(CC(=O)O)CC(=O)O)CC(=O)O
EDTA

試薬

なし

溶媒

[NH4+].[OH-]
ammonium hydroxide

反応条件

詳細条件
See reaction.notes.procedure_details.

後処理

  1. 1
    その他A precursor solution is prepared
  2. 2
    温度under reflux until a clear solution
  3. 3
    その他results

実験手順

A precursor solution is prepared by mixing 2.425 g of bismuth nitrate hexahydrate into 10 ml of 28% ammonium hydroxide solution containing 2 g of EDTA (ethylene diamine tetraacetic acid-sodium salt) under reflux until a clear solution results.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US07790137B2uspto-grants-2010_09