反応 #1793479

反応方程式

H(OCH2CH2)18OH

urea

dipropylene glycol

urea

→

dipropylene glycol monocarbamate

収率 76.0%

反応条件

後処理

1. 1
   その他prepared
2. 2
   workup.ADDITIONare added
3. 3
   温度After the mixture has cooled to about 100° C.
4. 4
   ろ過the catalyst is filtered off

実験手順

810 parts of a polyethylene ether-diol of molecular weight 810 (H(OCH2CH2)18OH) and 60 parts of urea are heated in a stirred apparatus for 5 hours at 150° C., whilst passing a stream of nitrogen through the apparatus. After this time, the degree of conversion is 92%. Thereafter, 2,680 parts of dipropylene glycol, 1,200 parts of urea and 100 parts of the nickel-containing exchanger prepared as described in Example 1(a) are added. The reaction mixture is heated for 16 hours at 155° C., whilst passing a stream of nitrogen through the apparatus. After the mixture has cooled to about 100° C., the catalyst is filtered off. 4,350 parts of the co-carbamate mixture, consisting of 24% of a polyethylene ether-diol monocarbamate H(OCH2CH)18OCONH2 and 76% of dipropylene glycol monocarbamate, are obtained.

出典