反応 #1747849

ord-34cbc220044e4ddfa08a0e8d4e75a805

反応方程式

CC(=O)N(O)CCCCCNC(=O)CCC(=O)N(O)CCCCCNC(=O)CCC(=O)N(O)CCCCCN
desferrioxamine
CC(=O)N(O)CCCCCNC(=O)CCC(=O)N(O)CCCCCNC(=O)CCC(=O)N(O)CCCCCN
desferrioxamine
O=C1OC2(c3ccc(O)cc3Oc3cc(O)ccc32)c2ccc(N=C=S)cc21
fluorescein isothiocyanate
O=C1OC2(c3ccc(O)cc3Oc3cc(O)ccc32)c2ccc(N=C=S)cc21
FITC
CC(=O)N(O)CCCCCNC(=O)CCC(=O)N(O)CCCCCNC(=O)CCC(=O)N(O)CCCCCN.O=C(O)c1ccccc1-c1c2ccc(=O)cc-2oc2cc(O)ccc12
Fluorescein Desferrioxamine

反応条件

詳細条件
See reaction.notes.procedure_details.

後処理

  1. 1
    その他to react for at least 24 hours at room temperature
  2. 2
    その他To separate fluorescently labeled desferrioxamine from free fluorescein and free desferrioxamine
  3. 3
    その他the mixture is separated
  4. 4
    洗浄are eluted in 2 mL fractions
  5. 5
    洗浄The fluorescein-desferrioxamine is eluted in the void volume of the column
  6. 6
    その他The first peak is collected
  7. 7
    その他used for preparing fluorescein-desferrioxamine, desferrioxamine, and rhodamine liposomes

実験手順

An aliquot of 120 mg of desferrioxamine and 233.64 mg of fluorescein isothiocyanate (FITC) are mixed in 50 mL of 0.1 M sodium carbonate pH 9.5. A molar ratio of 3:1 of FITC: desferrioxamine is used as described in Hentz et al. (1997) Anal. Chem. 69:4994-5000. The reaction mixture is wrapped in aluminum foil to avoid light exposure and allowed to react for at least 24 hours at room temperature. To separate fluorescently labeled desferrioxamine from free fluorescein and free desferrioxamine, the mixture is separated using a P-2 column (Bio-Rad) equilibrated in saline and samples are eluted in 2 mL fractions. The fluorescein-desferrioxamine is eluted in the void volume of the column. The first peak is collected and used for preparing fluorescein-desferrioxamine, desferrioxamine, and rhodamine liposomes.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US08029795B2uspto-grants-2011_10