反応 #1746629

反応方程式

dimethyldisulphide

1-octene

water

diethyl ether

→

methylthio-octane

収率 64.8%

溶媒

acetonitrile

反応条件

後処理

1. 1
   workup.ADDITIONof charge

実験手順

The procedure of Example 1 was repeated using dimethyldisulphide (96 mg; 1.02 mmol) and 1-octene (358 mg; 3.19 mmol) in acetonitrile (15 ml) at +1.20 V until 2 coulomb equivalents of charge had been passed. After the addition of water and extraction with diethyl ether, there was obtained 106 mg of methylthio-octane. Mass Spec. m/e 217 (M+) and 44 (100%). I.R. 3300 and 1650 cm-1.

出典