反応 #1714593

反応方程式

sodium cyclopentadienide

dibutyldichlorosilane

→

dibutylchloro(cyclopentadienyl)silane

溶媒

THF

THF

THF

反応条件

後処理

1. 1
   濃縮was concentrated under reduced pressure, and unreacted materials
2. 2
   workup.DISTILLATIONwere distilled away
3. 3
   その他The residue was used in the next step without further purification

実験手順

THF in a volume of 100 ml was added to 100 ml (200 mmol) of a 2M THF solution of sodium cyclopentadienide. The mixture was cooled to −78° C., and 100 ml of THF was added thereto. Further, 21.3 g (100 mmol) of dibutyldichlorosilane was gradually added dropwise. The mixture was stirred at room temperature for 24 hours and was concentrated under reduced pressure, and unreacted materials were distilled away. The residue was used in the next step without further purification.

出典