反応 #168442

反応方程式

methyl 3-ethylcyclopent-1-enecarboxylate

→

methyl 3-ethylcyclopentanecarboxylate

溶媒

methanol

反応条件

後処理

1. 1
   その他the mixture was purged with hydrogen for 10 minutes
2. 2
   その他Then reaction mixture
3. 3
   ろ過The reaction mixture was then filtered through a pad of celite
4. 4
   濃縮the filtrate was concentrated to dryness

実験手順

To a stirred solution of methyl 3-ethylcyclopent-1-enecarboxylate (1.60 g, 10.3 mmol) in methanol (15 mL) was added 10% Pd/C (100 mg), and the mixture was purged with hydrogen for 10 minutes. Then reaction mixture was then stirred at room temperature for 16 hours under a hydrogen atmosphere (balloon). The reaction mixture was then filtered through a pad of celite, and the filtrate was concentrated to dryness to afford methyl 3-ethylcyclopentanecarboxylate as a mixture of cis and trans isomers.

出典