反応 #161892

反応方程式

acrylonitrile

hexylamine

→

target compound

収率 98.9%

N,N-bis(2-cyanoethyl)hexylamine

収率 98.9%

反応条件

後処理

1. 1
   温度to cool to room temperature
2. 2
   抽出the mixed solution was extracted with 150 ml of ethyl acetate
3. 3
   その他The organic layer was separated from the solution
4. 4
   乾燥dried over anhydrous magnesium sulfate
5. 5
   workup.DISTILLATIONdistilled off the solvent

実験手順

20.1 g of acrylonitrile was added dropwise to an aqueous solution (150 ml) of 15.5 g of hexylamine at room temperature over 0.5 hours, and then the mixed solution was stirred at 70° C. for 3 hours. After standing to cool to room temperature, the mixed solution was extracted with 150 ml of ethyl acetate. The organic layer was separated from the solution, dried over anhydrous magnesium sulfate, and distilled off the solvent to obtain 31.4 g of a target compound as a colorless oily product.

出典