反応 #1596977

反応方程式

triethylamine

methacrylic acid chloride

1-hydroxyacenaphthene

→

acenaphthenyl methacrylate

溶媒

toluene

反応条件

後処理

1. 1
   workup.STIRRINGThe mixture was stirred at room temperature for 16 hours
2. 2
   workup.DISTILLATIONBy standard aqueous work-up and solvent distillation
3. 3
   その他a crude product was obtained
4. 4
   その他It was purified by column chromatography

実験手順

With stirring and ice cooling, 111 g of triethylamine was added to a mixture of 120 g of methacrylic acid chloride, 170 g of 1-hydroxyacenaphthene, and 1500 g of toluene. The mixture was stirred at room temperature for 16 hours. By standard aqueous work-up and solvent distillation, a crude product was obtained. It was purified by column chromatography, yielding the target compound, acenaphthenyl methacrylate.

出典