反応 #159264

反応方程式

4-fluoro-bromobenzene

4-methoxyphenyl boronic acid

→

4′-Fluoro-4-methoxybiphenyl

収率 89.0%

反応条件

後処理

1. 1
   その他mp 92-94° C. (lit.,2 94-96° C.)

実験手順

From 4-fluoro-bromobenzene and 4-methoxyphenyl boronic acid, yield 89%; mp 92-94° C. (lit.,2 94-96° C.); IR: 1504, 1276 and 1041; 1H NMR (400 MHz; CDCl3): 7.53-7.46 (4H, m), 7.11 (2H, t, J 8.7), 6.98 (2H, d, J 8.8) and 3.85 (3H, s); m/z (EI) 202 (95%, M+), 159 (100), 133 (90) and 69 (40)(Found: M+, 202.079. C13H11FO requires M, 202.079).

出典