反応 #1578173

ord-2c6b17ddbb764d77a36c39ebe30047bd

反応方程式

CCCCCCCCC1OCC(C)(C)CO1
CCCCCCCCC1OCC(C)(C)C
→
CC1(C)COC(CCCCCCCCB2OC(C)(C)C(C)(C)O2)OC1
CC1(C)COC(CCCCCCCCB2
収率 47.0%

反応物

CCCCCCCCC1OCC(C)(C)CO1
CCCCCCCCC1OCC(C)(C)CO1
CAS: 6974-80-7

試薬

C1=CCCC=CCC1.C1=CCCC=CCC1.C[OH2+].C[OH2+].[Ir].[Ir]
C1=CCCC=CCC1.C1=CCCC=CCC1.C[OH
CAS: 12148-71-9
CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C
CC1(C)OB(B2OC(C)(C)C(C)(C)O2)O
CAS: 73183-34-3
Cc1ccc2ccc3cccnc3c2n1
Cc1ccc2ccc3cccnc3c2n1
CAS: 3002-77-5

溶媒

C1CCCCCCC1
C1CCCCCCC1
CAS: 292-64-8

反応条件

温度
100°CELSIUS

出典

DOI: 10.1126/science.aba6146Borylation dataset from Roche