反応 #1578166

ord-ca87645145514f85b26f1107ce24c8c4

反応方程式

CCCCCCCCOCCCCCCCC
CCCCCCCCOCCCCCCCC
→
CCCCCCCCOCCCCCCCCB1OC(C)(C)C(C)(C)O1
CCCCCCCCOCCCCCCCCB1O
収率 43.0%
CC1(C)OB(CCCCCCCCOCCCCCCCCB2OC(C)(C)C(C)(C)O2)OC1(C)C
CC1(C)OB(CCCCCCCCOCC
収率 9.0%

反応物

CCCCCCCCOCCCCCCCC
CCCCCCCCOCCCCCCCC
CAS: 629-82-3

試薬

C1=CCCC=CCC1.C1=CCCC=CCC1.C[OH2+].C[OH2+].[Ir].[Ir]
C1=CCCC=CCC1.C1=CCCC=CCC1.C[OH
CAS: 12148-71-9
CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C
CC1(C)OB(B2OC(C)(C)C(C)(C)O2)O
CAS: 73183-34-3
Cc1ccc2ccc3cccnc3c2n1
Cc1ccc2ccc3cccnc3c2n1
CAS: 3002-77-5

溶媒

C1CCCCCCC1
C1CCCCCCC1
CAS: 292-64-8

反応条件

温度
100°CELSIUS

出典

DOI: 10.1126/science.aba6146Borylation dataset from Roche