反応 #155387

ord-e520dbfed13343b78f1b05d43e37b7af

反応方程式

COC(=O)c1c2ccccc2[n+](C)c2ccccc12.O=S(=O)([O-])C(F)(F)F
methyl 10-methylacridinium-9-carboxylate trifluoromethanesulfonate
COC(=O)C1c2ccccc2N(C)c2ccccc21
methyl 10-methylacridan-9-carboxylate

溶媒

反応条件

詳細条件
See reaction.notes.procedure_details.

実験手順

A solution of methyl 10-methylacridinium-9-carboxylate trifluoromethanesulfonate (75), 4.25 parts, in methanol is reduced as described in Example I to give 3.2 parts of methyl 10-methylacridan-9-carboxylate and the isolated product has the following structure confirmed by NMR.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US08822233B2uspto-grants-2014_09