反応 #1552057

反応方程式

2-methylpropionitrile

methacrylic acid

3-hydroxy-1 adamantylmethacrylate

9-anthrylmethylmethacrylate

→

HADMA

溶媒

tetrahydrofuran

反応条件

後処理

1. 1
   workup.ADDITIONwas added
2. 2
   その他The resulting solution was purged by nitrogen for 30 minutes before it
3. 3
   その他to 72° C.
4. 4
   その他for 18 hours
5. 5
   workup.ADDITIONadded drop-wise into 400 mL of de-ionized water
6. 6
   ろ過The solid was filtered with a frit funnel
7. 7
   洗浄washed with water (2×200 ml)
8. 8
   その他dried in a vacuum oven at 50° C. for 24 hours
9. 9
   その他to afford 3.1 gram of P1 as white solid

実験手順

To a mixture of methacrylic acid (0.775 g, 9 mmol), 3-hydroxy-1 adamantylmethacrylate (1.42 g, 6 mmol), 9-anthrylmethylmethacrylate (1.38 g, 5 mmol) in 20 mL of tetrahydrofuran (THF) was added 2,2′-azobis(2-methylpropionitrile (0.24 g, 1.5 mmol). The resulting solution was purged by nitrogen for 30 minutes before it was heats to 72° C. for 18 hours under nitrogen. The solution was then cooled to room temperature and added drop-wise into 400 mL of de-ionized water. The solid was filtered with a frit funnel, washed with water (2×200 ml) and dried in a vacuum oven at 50° C. for 24 hours to afford 3.1 gram of P1 as white solid.

出典