反応 #1547447

反応方程式

p-methoxybenzyl chloride

N,N-dimethylaniline

sodium hexafluoroantimonate

→

titled compound

N-(p-methoxybenzyl)-N,N-dimethylanilinium hexafluoroantimonate

溶媒

methanol

反応条件

後処理

1. 1
   その他After the reaction
2. 2
   その他the solvent was evaporated in vacuo and ether/water
3. 3
   workup.ADDITIONwas added to the residue
4. 4
   抽出to extract unreacted reactans in the etherial layer
5. 5
   workup.ADDITIONTo the aquous layer containing the ammonium chloride
6. 6
   ろ過filtered
7. 7
   洗浄washed
8. 8
   その他dried

実験手順

4,698 g (0.03 mol) of p-methoxybenzyl chloride and 3,638 g (0.03 mol) of N,N-dimethylaniline were reacted in 40 ml of methanol at 40° C. for 3 days. After the reaction, the solvent was evaporated in vacuo and ether/water was added to the residue to extract unreacted reactans in the etherial layer. To the aquous layer containing the ammonium chloride was added 7.77 g (0.03 mol) of sodium hexafluoroantimonate. The resulting crystals were suction filtered, washed and dried to give the titled compound.

出典