反応 #1483120

反応方程式

2-(2-Hydroxyphenyl)-1,10-phenanthroline

2-(2-Hydroxyphenyl)-1,10-Phenanthroline

lithium t-butoxide

→

Lithium 2-(1,10-Phenanthrolin-2-yl)-Phenolate

溶媒

tetrahydrofuran

反応条件

後処理

1. 1
   workup.STIRRINGThe precipitated product was stirred at room temperature in the reaction mixture for 1 hour
2. 2
   その他the reaction
3. 3
   ろ過The lithium 2-(1,10-phenanthrolin-2-yl)-phenolate was filtered off
4. 4
   洗浄washed well with diethyl ether
5. 5
   その他air-dried

実験手順

2-(2-Hydroxyphenyl)-1,10-phenanthroline (4) (20 g, 73.45 mMole) was dissolved in tetrahydrofuran and with good stirring treated with lithium t-butoxide (5.65 g, 88.14 mMole). The precipitated product was stirred at room temperature in the reaction mixture for 1 hour to complete the reaction. The lithium 2-(1,10-phenanthrolin-2-yl)-phenolate was filtered off, washed well with diethyl ether and air-dried. Yield 21 g.

出典