反応 #1482014

ord-9888c9bb701c4734bf16bb6439970448

反応方程式

C=C(C)C(=O)OC
methyl methacrylate
C=CC(=O)OCCCC
butyl acrylate
C=CC(=O)OCCC(=O)O
β-carboxyethyl acrylate
CCCCCCCCCCCCS
dodecylthiol
O=S(=O)([O-])OOS(=O)(=O)[O-].[NH4+].[NH4+]
ammonium persulfate
→
C=C(C)C(=O)OC.C=CC(=O)OCCC(=O)O.C=CC(=O)OCCCC
MMA BA β-CEA

反応物

C=C(C)C(=O)OC
methyl methacrylate
C=CC(=O)OCCCC
butyl acrylate
C=CC(=O)OCCC(=O)O
β-carboxyethyl acrylate
CCCCCCCCCCCCS
dodecylthiol
O=S(=O)([O-])OOS(=O)(=O)[O-].[NH4+].[NH4+]
ammonium persulfate

試薬

なし

溶媒

O
water
O
water
O
water

反応条件

詳細条件
See reaction.notes.procedure_details.

後処理

  1. 1
    その他was prepared
  2. 2
    その他to form a monomer latex suspension
  3. 3
    workup.ADDITIONThe monomer latex suspension is then added dropwise over the course of 3 hours into the first aqueous solution
  4. 4
    その他Polymerization
  5. 5
    workup.ADDITIONafter completion of the addition

実験手順

An aqueous solution of DOWFAX surfactant (0.68 g) in 514 g of deionized water was heated to 76° C., and an initiator solution of 8.2 g of ammonium persulfate in 45 g of deionized water was added. A second aqueous solution of 10.8 g DOWFAX, 257 g deionized water was prepared, and a monomer solution of 467.1 g methyl methacrylate (MMA), 168.4 g butyl acrylate (BA), 30.9 g of β-carboxyethyl acrylate (β-CEA) and 7.5 mL dodecylthiol was added to form a monomer latex suspension. The monomer latex suspension is then added dropwise over the course of 3 hours into the first aqueous solution. Polymerization was continued for another 4 hours after completion of the addition. A poly(MMA/BA/β-CEA) polymer latex with a solids content of 45% was obtained.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US07349147B2uspto-grants-2008_03