反応 #1470424

反応方程式

1-oxyl-2,2,6,6-tetramethyl-4-hydroxypiperidine

epichlorohydrin

→

title compound

1-Oxyl-2,2,6,6-tetramethyl-4-glycidyloxypiperidine

溶媒

sodium hydroxide

toluene

反応条件

後処理

1. 1
   その他is reacted together
2. 2
   乾燥The organic phase is dried over anhydrous magnesium sulfate
3. 3
   濃縮concentrated

実験手順

A vigorously stirred two phase solution of 1-oxyl-2,2,6,6-tetramethyl-4-hydroxypiperidine, epichlorohydrin, tetrabutylammonium bromide in 50% aqueous sodium hydroxide and toluene is reacted together. The organic phase is dried over anhydrous magnesium sulfate and concentrated to yield the title compound as a low melting red solid after column chromatography.

出典