反応 #1435722

反応方程式

potassium hydride

(3-trimethylsiloxy-propyl)-cyclopentadiene

→

potassium (3-trimethylsiloxypropyl)-cyclopentadienide

収率 70.0%

溶媒

tetrahydrofurane

tetrahydrofurane

反応条件

後処理

1. 1
   workup.ADDITIONis added
2. 2
   温度The reaction is maintained
3. 3
   濃縮Subsequently, the resulting suspension is concentrated to dryness
4. 4
   その他leaving an oily solid that, when it
5. 5
   洗浄is washed with hexane
6. 6
   その他gives a cream-coloured solid

実験手順

To a suspension of 0.4 g (10 mmol) of potassium hydride in tetrahydrofurane, 1.96 g (10 mmol) of a (3-trimethylsiloxy-propyl)-cyclopentadiene in tetrahydrofurane is added. The reaction is maintained under stirring for 2 hours. Subsequently, the resulting suspension is concentrated to dryness, leaving an oily solid that, when it is washed with hexane, gives a cream-coloured solid. (1.6 g, 7 mmol. Yield:70%).

出典