反応 #1365696

反応方程式

cesium carbonate

Ascorbic acid

isopropyl alcohol

carbon dioxide

→

cesium ascorbate

収率 192.0%

溶媒

water

反応条件

後処理

1. 1
   workup.WAITAfter standing for several hours
2. 2
   ろ過the precipitate was filtered
3. 3
   洗浄washed with isopropyl alcohol
4. 4
   その他dried

実験手順

Ascorbic acid (5 g, 28.4 mmol) was dissolved in 20 ml of water, followed by slow addition of cesium carbonate (4.63 g, 14.2 mmol) in the temperature range of 0 to 5° C. 40 ml of isopropyl alcohol was slowly added to the reaction mixture when the generation of carbon dioxide completely stopped. After standing for several hours, the precipitate was filtered and washed with isopropyl alcohol, and dried to give 8.4 g of the cesium ascorbate as a white solid (yield 95%).

出典