反応 #1350565

反応方程式

N-butyl-N-cyclooctylpyrrolidinium iodide salt

hydroxide

→

N-butyl-N-cyclooctylpyrrolidinium hydroxide

溶媒

water

反応条件

後処理

1. 1
   workup.ADDITIONof Ion Exchange Resin OH (BIO RAD® AG1-X8) was added
2. 2
   ろ過The mixture was filtered
3. 3
   洗浄the solids were rinsed with an additional 250 ml
4. 4
   ろ過The original mixture was filtered

実験手順

N-butyl-N-cyclooctylpyrrolidinium iodide salt (95 gms., 0.26 mole) was dissolved in 300 ml. water in a 1000 ml. plastic bottle. To the solution, 300 gms. of Ion Exchange Resin OH (BIO RAD® AG1-X8) was added and the mixture was stirred at room temperature overnight. The mixture was filtered and the solids were rinsed with an additional 250 ml. of water. The original mixture was filtered and the rinse were combined and a small amount was titrated with 0.1N HCl to indicate the presence of 0.24 mol hydroxide (0.24 mol N-butyl-N-cyclooctylpyrrolidinium hydroxide) in the solution.

出典