反応 #1340563

ord-50762937bfe84de5b8de680d0acea52e

反応方程式

c1ccc2c(c1)c1ccccc1c1ccccc21
Triphenylene
[Al+3].[Cl-].[Cl-].[Cl-]
AlCl3
CC(=O)Cl
CH3COCl
→
CC(=O)c1cccc2c3ccccc3c3ccccc3c12
acetyltriphenylene
収率 97.0%

反応物

c1ccc2c(c1)c1ccccc1c1ccccc21
Triphenylene
[Al+3].[Cl-].[Cl-].[Cl-]
AlCl3
CC(=O)Cl
CH3COCl

試薬

なし

溶媒

ClCCl
CH2Cl2

反応条件

詳細条件
See reaction.notes.procedure_details.

実験手順

Triphenylene (1 equivalent) is reacted at 0° C. with 2.1 equivalents of AlCl3 and 21.0 equivalents of CH3COCl in CH2Cl2. After stirring at room temp. for 3 hours, the reaction product (acetyltriphenylene) was obtained in 97% yield, and is used in step b).

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US08455112B2uspto-grants-2013_06