反応 #1328428

反応方程式

oxygen

p-xylene

N-acetoxyphthalimide

acetic acid

→

p-toluic acid

terephthalic acid

反応条件

実験手順

A mixture of 2 mmol of p-xylene, 0.4 mmol of N-acetoxyphthalimide, 0.01 mmol of cobalt(II) acetate and 5 ml of acetic acid was stirred at 100° C. in an atmosphere of oxygen gas (1 atm=0.1 MPa) for 14 hours and thereby yielded terephthalic acid and p-toluic acid in yields of 91% and 1%, respectively.

出典