反応 #1261632

反応方程式

1-methylnaphthalene

N-bromosuccinimide

benzoyl peroxide

→

1-(bromomethyl)naphthalene

収率 94.0%

溶媒

carbon tetrachloride

反応条件

後処理

1. 1
   温度while heating
2. 2
   温度refluxing
3. 3
   その他The deposit was removed by filtration
4. 4
   濃縮the filtrate was concentrated

実験手順

A mixture of 52.35 g (368.1 mmol) of 1-methylnaphthalene, 68.79 g (368.5 mmol) of N-bromosuccinimide (NBS), 0.45 g (1.86 mmol) of benzoyl peroxide (BPO) and 250 ml of carbon tetrachloride was stirred for 6 hours while heating and refluxing. The deposit was removed by filtration, and the filtrate was concentrated to obtain 84.64 g (purity: 90.4%, yield: 94%) of an oily crude product of 1-(bromomethyl)naphthalene.

出典