反応 #1256745

反応方程式

Compound 40a

Isobutyldiisopropylsilane

diisopropylchlorosilane

→

Compound 44a

Cyclopropyldiisopropylsilane

溶媒

反応条件

実験手順

The procedure of synthesizing Compound 40a was repeated, except that diisopropylchlorosilane (4.10 mL, 96.0 mmol) and cyclopropylmagnesium bromide THF solution (1.0M, 100 mL) were employed, whereby the Compound 44a was obtained as a colorless liquid (boiling point; 35 mmHg, 86 to 89° C. fraction, 1.84 g, 50%).

出典