反応 #1255206

反応方程式

Diphenyliodonium chloride

trimethyl phosphate

→

target compound

収率 81.6%

diphenyliodonium dimethylphosphonate

収率 81.6%

反応条件

後処理

1. 1
   workup.DISSOLUTIONAfter the reactants were dissolved
2. 2
   温度the mixture was cooled
3. 3
   その他to thereby yield solid matter
4. 4
   洗浄The solid matter was washed with ether

実験手順

Diphenyliodonium chloride (315 mg; 1 mmol) and trimethyl phosphate (1 g) were stirred at 170° C. for 10 minutes. After the reactants were dissolved, the mixture was cooled, to thereby yield solid matter. The solid matter was washed with ether, to thereby yield 250 mg of the target compound as white crystals (yield: 81.6%). The anion content of the resultant compound was determined by ion chromatography. The chloride anion content was determined to be not greater than 10 ppm.

出典