反応 #1244245

ord-1f167e30f6cb4e04ac00ef2005a6fffe

反応方程式

O=C(F)C(F)(OC(F)(F)C(F)(F)C(F)(F)F)C(F)(F)F
FCOCF(CF3)OCF2CF2CF3
O=S(=O)(F)CCOCCO
FSO2CH2CH2OCH2CH2OH
O=C(OCCOCCS(=O)(=O)F)C(F)(OC(F)(F)C(F)(F)C(F)(F)F)C(F)(F)F
FSO2CH2CH2OCH2CH2OCOCF(CF3)OCF2CF2CF3

反応条件

詳細条件
See reaction.notes.procedure_details.

実験手順

FCOCF(CF3)OCF2CF2CF3 obtained in Example 4 was reacted with FSO2CH2CH2OCH2CH2OH under the same conditions as in the above esterification to obtain FSO2CH2CH2OCH2CH2OCOCF(CF3)OCF2CF2CF3. The obtained FSO2CH2CH2OCH2CH2OCOCF(CF3) OCF2CF2CF3 was fluorinated under the same conditions as in the above fluorination step to obtain FSO2CF2CF2OCF2CF2OCOCF(CF3)OCF2CF2CF3. The obtained FSO2CF2CF2OCF2CF2OCOCF(CF3) OCF2CF2CF3 was decomposed under the same conditions as in the above decomposition step to obtain FSO2CF2CF2OCF2COF and FCOCF(CF3)OCF2CF2CF3.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: USRE041806E1uspto-grants-2010_10