反応 #1186

反応方程式

ammonium hydroxide

vinyl acetate

→

vinyl alcohol

vinyl acetate

溶媒

methanol

反応条件

後処理

1. 1
   その他the preparation of high TFE content copolymer
2. 2
   workup.ADDITIONwas added
3. 3
   workup.ADDITIONthe TFE addition rate
4. 4
   その他2580 g of a 25.0 wt % solids colloidal dispersion was obtained
5. 5
   workup.WAITAfter several weeks at room temperature with occasional shaking
6. 6
   温度the resulting solution was heated
7. 7
   その他to remove the reaction by-products

実験手順

This Example shows the preparation of high TFE content copolymer. The conditions of Example III were repeated except that a total of 470 mg of APS was added, the TFE addition rate was 0.01 lb/min (4.5 g/min), the vinyl acetate addition rate was 2 ml/min., and the final agitation rate was 80 rpm. 2580 g of a 25.0 wt % solids colloidal dispersion was obtained. To 100 g of the isolated, dried polymer was added 500 ml of methanol and 40 ml of concentrated ammonium hydroxide. After several weeks at room temperature with occasional shaking, the resulting solution was heated to remove the reaction by-products and there was obtained a hazy, viscous solution of 19 wt % solids of approximate composition 82 wt % TFE, 16 wt % vinyl alcohol, and 2 wt % vinyl acetate. Upon evaporation of the solvent at 50° C. in a vacuum oven for one day, a clear, somewhat rubbery melt fabricable polymer was obtained.

出典