反応 #1106650

ord-eb992f7f0bdc4e959670fa4f5762e7f8

反応方程式

CC(N)=O
acetamide
O=S(=O)([N-]S(=O)(=O)C(F)(F)F)C(F)(F)F.[Li+]
LiTFSI
→
CC(N)=O.O=S(=O)([N-]S(=O)(=O)C(F)(F)F)C(F)(F)F.[Li+]
acetamide LiTFSI
収率 152.0%

反応物

CC(N)=O
acetamide
O=S(=O)([N-]S(=O)(=O)C(F)(F)F)C(F)(F)F.[Li+]
LiTFSI

試薬

なし

反応条件

詳細条件
See reaction.notes.procedure_details.

後処理

  1. 1
    その他moisture was removed
  2. 2
    workup.WAITin a vacuum oven for 3 days

実験手順

5 g of purified acetamide and 6 g of LiTFSI were put into a round bottom flask and slowly stirred for 12 hours at a normal temperature under a nitrogen circumstance, and then moisture was removed therefrom in a vacuum oven for 3 days, thereby obtaining 11 g of acetamide-LiTFSI eutectic mixture.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US08715866B2uspto-grants-2014_05