反応 #1106648

ord-a3b55992030d4bda86d4712a30e702de

反応方程式

c1cncnc1
pyrimidine
O=S(=O)([N-]S(=O)(=O)C(F)(F)F)C(F)(F)F.[Li+]
LiTFSI
→
O=S(=O)([N-]S(=O)(=O)C(F)(F)F)C(F)(F)F.[Li+].c1cncnc1
pyrimidine LiTFSI
収率 140.8%

反応物

c1cncnc1
pyrimidine
O=S(=O)([N-]S(=O)(=O)C(F)(F)F)C(F)(F)F.[Li+]
LiTFSI

試薬

なし

反応条件

温度
40°CELSIUS
詳細条件
See reaction.notes.procedure_details.

実験手順

10 g of purified pyrimidine and 11.94 g of LiTFSI were put into a round bottom flask and slowly stirred for 1 hour under a nitrogen circumstance of 40° C., thereby obtaining 21.5 g of pyrimidine-LiTFSI eutectic mixture.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US08715866B2uspto-grants-2014_05