反応 #1076750

ord-0c3ac33c41a745a1b76c3f1c3d78483d

反応方程式

[Cl-].[Cl-].[Cl-].[Cr+3]
chromium chloride
CC(=O)N[C@@H](CS)C(=O)O
N-acetyl cysteine
→
CC(=O)N[C@@H](CS)C(=O)O.[Cr]
Chromium N-Acetyl Cysteine

反応物

[Cl-].[Cl-].[Cl-].[Cr+3]
chromium chloride
CC(=O)N[C@@H](CS)C(=O)O
N-acetyl cysteine

試薬

なし

溶媒

O
water
O
water

反応条件

温度
40°CELSIUS
詳細条件
See reaction.notes.procedure_details.

後処理

  1. 1
    その他to get a green solution
  2. 2
    workup.ADDITIONwere added

実験手順

One half gram (1.85 mmole) of chromium chloride (CrCl3) was dissolved in 30 ml of deionized water to get a green solution. 1.5 g (9.2 mmole) of N-acetyl cysteine (NAC) was dissolved in 40 ml of deionized water were added, and the mixture was stirred for 3 hours at 40° C. until the solution turned dark green-blue.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US06458351B2uspto-grants-2002_10