反応 #1076749

ord-df729fb9ffa9459e9c507d3598e19146

反応方程式

[Cl-].[Cl-].[Cl-].[Cr+3]
chromium chloride
N[C@@H](CCC(=O)N[C@@H](CS)C(=O)NCC(=O)O)C(=O)O
glutathione
→
N[C@@H](CCC(=O)N[C@@H](CS)C(=O)NCC(=O)O)C(=O)O.[Cr]
Chromium Glutathione

反応物

[Cl-].[Cl-].[Cl-].[Cr+3]
chromium chloride
N[C@@H](CCC(=O)N[C@@H](CS)C(=O)NCC(=O)O)C(=O)O
glutathione
—
Cr GSH

試薬

なし

溶媒

O
water
O
water

反応条件

温度
40°CELSIUS
詳細条件
See reaction.notes.procedure_details.

後処理

  1. 1
    その他to get a green solution
  2. 2
    workup.ADDITIONwere added

実験手順

One gram (3.7 mmole) of chromium chloride (CrCl3) was dissolved in 40 ml of deionized water to get a green solution. 4.6 g (15 mmole) of glutathione (GSH) was dissolved in 40 ml of deionized water were added, the pH of the reaction mixture adjusted to 6, and the reaction mixture was stirred for 3 hours at 40° C. until the solution turned violet. The absorbance peaks for Cr-GSH are 410 and 550 nm.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US06458351B2uspto-grants-2002_10