反応 #10703

反応方程式

2,6-diisopropylaniline

pyridine

2-(9-Anthracenyl)-4-methylphenol

NaOH

phenolate

→

phenol

2-(2′,6′-Diisopropylphenylazo)-4-methyl-6-(9-anthracenyl)phenol

溶媒

benzene

water

反応条件

後処理

1. 1
   洗浄In this case, the product was eluted with ether:hexanes (1:10)

実験手順

This phenol was prepared, as described above, from a theoretical yield of 3.9 mmol of diazotized 2,6-diisopropylaniline and a phenolate solution comprised of 2-(9-Anthracenyl)-4-methylphenol (0.63 g), water (20 mL), NaOH (20 mmol), pyridine (2 mL), and benzene (4 mL). In this case, the product was eluted with ether:hexanes (1:10). Yield=0.30 g (29%).

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