Réaction #962027

ord-2009e5a7c6f5489d9e57344a185cf828

Équation de réaction

C1=CC2C(C1)C1CC2C2C3C=CC(C3)C12
TCPD
C1=CC2C3C=CC(C3)C2C1
dicyclopentadiene
C1=CC2C(C1)C1CC2C2C3C=CC(C3)C12
tricyclopentadiene
C1=CC2C3C=CC(C3)C2C1
DCPD
→
C1=CC2C(C1)C1CC2C2C3C=CC(C3)C12.C1=CC2C3C=CC(C3)C2C1
polymer
C1=CC2C(C1)C1CC2C2C3C=CC(C3)C12.C1=CC2C3C=CC(C3)C2C1
Dicyclopentadiene Tricyclopentadiene

Réactifs

C1=CC2C(C1)C1CC2C2C3C=CC(C3)C12
TCPD
C1=CC2C3C=CC(C3)C2C1
dicyclopentadiene
C1=CC2C(C1)C1CC2C2C3C=CC(C3)C12
tricyclopentadiene
C1=CC2C3C=CC(C3)C2C1
DCPD

Réactifs

Aucun

Conditions de réaction

Conditions détaillées
See reaction.notes.procedure_details.

Traitement

  1. 1
    Autrepolymerization

Mode opératoire

As shown in Table 1 below, polymerization was carried out at the different molar ratios of dicyclopentadiene (DCPD) to tricyclopentadiene (TCPD) of 100:0 (Example 1), 90:10 (Example 2), 80:20 (Example 3), 70:30 (Example 4), 65:35 (Example 5), and 60:40 (Example 6) under conditions of the total molar number of DCPD and TCPD being fixed to 18.8 mmol, after which hydrogenation was conducted, yielding 2.1 g, 2.2 g, 2.6 g, 2.9 g, 3.0 g, and 3.0 g of polymer materials, respectively.

Source

DOI: 10.6084/m9.figshare.5104873.v1Brevet: US08981026B2uspto-grants-2015_03