Réaction #955973

ord-13e7ba3cd63348289f73c7bedc88ebb9

Équation de réaction

[Cl-].c1ccc([P+](Cc2cccc3ccccc23)(c2ccccc2)c2ccccc2)cc1
(1-napthylmethyl)triphenylphosphonium chloride
O=Cc1ccc(Br)cc1
4-bromobenzaldehyde
→
Brc1ccc2ccc3c4ccccc4ccc3c2c1
3-Bromochrysene

Réactifs

[Cl-].c1ccc([P+](Cc2cccc3ccccc23)(c2ccccc2)c2ccccc2)cc1
(1-napthylmethyl)triphenylphosphonium chloride
O=Cc1ccc(Br)cc1
4-bromobenzaldehyde

Réactifs

Aucun

Conditions de réaction

Conditions détaillées
See reaction.notes.procedure_details.

Mode opératoire

3-Bromochrysene was prepared from (1-napthylmethyl)triphenylphosphonium chloride and 4-bromobenzaldehyde using the procedure described in Example 1, part a.

Source

DOI: 10.6084/m9.figshare.5104873.v1Brevet: US08968883B2uspto-grants-2015_03