Réaction #95320

Équation de réaction

hydrogen peroxide

tetrachloroacetone

cyclooctene

chloroform

→

cyclooctene oxide

Rendement 83.0%

Solvants

water

Conditions de réaction

Traitement

1. 1
   AutreWater was removed continuously as it
2. 2
   Autrewas formed, over a period of 4 hours
3. 3
   Températureof heating
4. 4
   AutreThe organic phase was then separated from the aqueous phase

Mode opératoire

There were added 13.68 parts of a 50% aqueous hydrogen peroxide to a refluxing mixture of 3.92 parts of tetrachloroacetone, 11.58 parts of cyclooctene and 149 parts of chloroform. Water was removed continuously as it was formed, over a period of 4 hours of heating. The removed water was then added to the reaction mixture. The organic phase was then separated from the aqueous phase. Based on VPC analysis there was obtained an 83% yield of cyclooctene oxide.

Source