Réaction #83155

ord-e69dd5f7a54a4a5caa414d8ac3392e56

Équation de réaction

Oc1cc(F)c(F)c(F)c1
3,4,5-trifluorophenol
CCCCC[Si]1(c2ccccc2)CCC(c2ccc(C(=O)O)cc2)CC1
4-(4-phenyl-4-n-pentyl-4-silacyclohexyl)benzoic acid
→
CCCCC[Si@H]1CC[C@H](c2ccc(C(=O)Oc3cc(F)c(F)c(F)c3)cc2)CC1
(3,4,5-trifluorophenyl) trans-4-(4-n-pentyl-4-silacyclohexyl)benzoate

Réactifs

Oc1cc(F)c(F)c(F)c1
3,4,5-trifluorophenol
CCCCC[Si]1(c2ccccc2)CCC(c2ccc(C(=O)O)cc2)CC1
4-(4-phenyl-4-n-pentyl-4-silacyclohexyl)benzoic acid

Réactifs

Aucun

Conditions de réaction

Conditions détaillées
See reaction.notes.procedure_details.

Traitement

  1. 1
    Autreobtaining the intended product

Mode opératoire

The general procedure of Example 3 was repeated using 3,4,5-trifluorophenol and 4-(4-phenyl-4-n-pentyl-4-silacyclohexyl)benzoic acid, thereby obtaining the intended product.

Source

DOI: 10.6084/m9.figshare.5104873.v1Brevet: US05624601uspto-grants-1997_04